Sunday, February 28, 2016

Barc Chemical pattern

Barc asks questions that are easy to be answered and checks subject understanding of the examinee.

A good student shall be able to answer 100 questions in given 2 hrs.

Previous Year Questions Of Barc   Chemical 2015 .

Here is a few of questions of Barc chemical on the basis of memory.

1. For which of the element the amplitude ratio is one and phase lag increases with frequency.

A) Transportation lag
B) valve
C) proportional controller
D) none of these

2.
A pure capacitive system can be made by adding a ------ to outlet of a tank.

A. Constant volumetric flow pump
B. Square root valve
C. Linear valve
D. Flow controller

3. The absorption factor is-----

4. % free so3 in 104.8 % H2SO4 is----
A) 20
B) 10
D) 30
C) 40

5. A question was to calculate volume of PFR given the flow rate and the concentration temperature and the reaction was 2nd order.

6. A question was to calculate height of fluid transported by a pump given the power and fanning friction factor.

BARC Chemical 2015 Cut Off

The cutoff score for being short listed for the selection interview was 91 percentile .

Wednesday, February 17, 2016

Gate 2016 Chemical :: Unofficial Solution And Answer Key

Q. 1 – Q. 5 carry one mark each.

Q.1 The volume of a sphere of diameter 1 unit is ________ than the volume of a cube of side 1 unit.

(A) least          (B) less            (C) lesser                                                           (D) low

Ans:: B) Less

Q.2 The unruly crowd demanded that the accused be _____________ without trial.

(A) hanged      (B) hanging     (C) hankering      (D) hung

Ana:: A) Hanged


Q.3 Choose the statement(s) where the underlined word is used correctly:

(i) A prone is a dried plum.
 (ii) He was lying prone on the floor.
(iii) People who eat a lot of fat are prone to heart disease

(A) (i) and (iii) only     (B) (iii) only        (C) (i) and (ii) only         (D) (ii) and (iii) only

And:: B) 3 only

Q.4 Fact: If it rains, then the field is wet.

 Read the following statements:
(i) It rains
(ii) The field is not wet
 (iii) The field is wet
 (iv) It did not rain

Which one of the options given below is NOT logically possible, based on the given fact?

(A) If (iii), then (iv).
(B) If (i), then (iii).
 (C) If (i), then (ii).
(D) If (ii), then (iv).


And:: C)


Q.5 A window is made up of a square portion and an equilateral triangle portion above it. The base of the triangular portion coincides with the upper side of the square. If the perimeter of the window is 6 m, the area of the window in m2 is ___________.

(A) 1.43         (B) 2.06        (C) 2.68       (D) 2.88


Ans:: C)


Q. 6 – Q. 10 carry two marks each

Q.6  Students taking an exam  are divided into  two groups,  P  and  Q  such that each  group has the  same number of  students. The performance  of each of the students in a test was evaluated out of 200 marks. It  was observed that the  mean  of group  P  was 105, while that of group  Q  was 85. The standard deviation of group  P  was 25,  while that of  group  Q  was  5. Assuming  that the  marks were distributed on  a normal  distribution,  which of  the following statements will have the highest probability of  being  TRUE? 

(A)   No student in group Q scored less marks than any student in group P.
(B)   No student in group P scored less marks than any student in group Q.
(C)   Most students of group Q scored marks in a narrower range than students in group P. 
(D)   The median of the marks of group P is 100.  

Q.7. A smart city  integrates all  modes of transport, uses clean energy  and promotes  sustainable use of resources. It also uses technology  to  ensure safety  and security  of the city, something which critics argue, will lead to a surveillance state.  

Which of the following can be logically inferred from the above paragraph? 

(i) All smart  cities encourage  the formation of surveillance states. 
(ii) Surveillance is an integral part of a smart city. 
(iii) Sustainability and surveillance go hand in  hand in  a smart city. 
(iv) There is a perception that smart cities promote surveillance.

(A)   (i) and (iv) only.                (B)   (ii) and (iii) only 

(C)   (iv) only.                              (D)   (i) only


Q.8 Find the missing sequence in the letter series.

 B, FH, LNP, _ _ _ _. 

(A)   SUWY     (B)   TUVW.    (C)   TVXZ.     (D)   TWXZ 

Q.9 The binary  operation  □  is  defined as  a  □  b  =  ab+(a+b), where  a  and  b  are any two real numbers. The value of the identity  element of this operation, defined as the number  x  such  that  a  □  x  =  a, for any a, is           . 

(A)   0             (B)   1.         (C)   2.             (D)   10


Ans:: A) 0

Q.10. No solution available for this question.


                  END OF THE QUESTION PAPER


                  ::Chemical Engineering Section::

Q. 1 – Q. 25 carry one mark each.

 Q.1 Which one of the following is an iterative technique for solving a system of simultaneous linear algebraic equations?
 (A)  Gauss elimination
 (B)  Gauss-Jordan 
(C)  Gauss-Seidel
 (D)  LU decomposition

And:: D)

Q.4  A liquid mixture of ethanol and water is flowing as inlet stream P into a stream splitter.  It is split into two streams, Q and R, as shown in the figure below.  

                                                   
                                      
The flowrate of P, containing 30 mass% of ethanol, is 100 kg/h. What is the least number of additional specification(s) required to determine the mass flowrates and compositions (mass%) of the two exit streams?  

(A)  0               (B)  1              (C)   2.           (D)   3 

Ans:: B)

Q.7 
In  a cyclone separator used  for  separation of  solid particles  from  a dust laden  gas,  the  separation factor is  defined as the ratio of the centrifugal force to  the  gravitational force acting  on  the  particle. Sr  denotes the separation factor  at a  location (near the wall)  that  is  at a  radial  distance  r  from  the centre  of the  cyclone.  Which one of  the  following  statements is INCORRECT? 

(A)    S r  depends  on  mass  of  the particle 
(B)   S rdepends on  the acceleration  due to  gravity (C)   S r  depends  on  tangential velocity  of  the  particle 
(D)   S rdepends on the radial location ( r ) of the particle


Ans:: B)

Q.8. A vertical  cylindrical  vessel has  a layer  of  kerosene  (of  density  800  kg/m3) over a  layer of  water (of density  1000  kg/m3).   L-shaped  glass tubes are  connected to the  column  30  cm  apart.   The  interface between  the two  layers lies  between  the  two  points  at  which the L-tubes  are connected. The levels (in cm) to which the liquids rise in the respective tubes are shown in the figure below. 






The distance  (x  in cm,  rounded off  to  the first  decimal  place)  of  the interface  from  the point at which the lower L-tube is connected is _______ 

Ans:: 19.9 cm

Q.11.   A  binary  liquid mixture  of benzene and  toluene  contains 20  mol%  of  benzene. At  350  K the vapour pressures  of  pure  benzene and pure toluene are 92  kPa and  35  kPa, respectively. The  mixture follows Raoult’s law. The equilibrium  vapour  phase  mole fraction (rounded  off to the second decimal place) of benzene in contact with this liquid mixture at 350 K is _______

Ans::  0.39
                                 
                   

Ans:: D)




Q.13  For what value  of  Lewis  number,  the  wet-bulb temperature and adiabatic saturation  temperature  are nearly  equal? 

(A)     0.33        (B)   0.5          (C)  1.        (D)    2 


Ans:: C)

Q.15 The variations of the concentrations (CA, CR and CS) for three species (A, R and S) with time, in an isothermal homogeneous batch reactor are shown in the figure below. 







Select the reaction scheme that correctly represents the above plot. The numbers in the reaction schemes shown below, represent the first order rate constants in unit of s‒1.  





Ans:: C)

Q.17


Ans:: D)


Q.16 Hydrogen iodide decomposes through the reaction 2HI⇋ H2 + I2. The value of the universal gas constant R is 8.314 J mol‒1K‒1. The activation energy for the forward reaction is 184000 J mol‒1. The ratio (rounded off to the first decimal place) of the forward reaction rate at 600 K to that at 550 K is _______ 


Ans::  28.6






Q.18  What  is the order  of  response exhibited by  a  U-tube  manometer? 


(A)     Zero  order 
 (C)   Second  order 
(B)     First  order  
(D)   Third order 


Ans:: c)


Q.19  A system  exhibits  inverse response  for a unit step  change  in  the input.  Which  one  of the following statement must  necessarily be  satisfied? 

(A)   The transfer function  of  the  system  has at  least  one negative  pole 
(B)   The transfer function of the system  has  at least  one  positive  pole
 (C)   The transfer function of the system  has at  least one negative zero 
(D)   The transfer function of the system has at least one positive zero 

Ans:: A)





Ans:: A) 40

Q.21  Standard pipes of  different schedule  numbers and standard  tubes  of different BWG numbers  are available in  the  market. For  a pipe  / tube  of  a given nominal  diameter,  which one  of the  following statements is  TRUE?   

(A)  Wall thickness  increases with increase  in  both  the schedule number  and  the  BWG number 
(B) Wall thickness increases with increase in the schedule number and decreases with increase in  the BWG number 
(C) Wall  thickness decreases  with  increase  in  both  the  schedule  number  and  the  BWG  number 
(D) Neither the schedule number, nor the BWG number has any relation to wall thickness 


Ans::  B)


Q.22  Terms  used in  engineering  economics  have  standard definitions  and  interpretations.  Which one of the following statements  is  INCORRECT?


 (A) The profitability  measure  ‘return on  investment’ does not consider the time  value  of  money
 (B)   A  cost  index is  an  index value for a  given  time showing  the cost  at that time relative to  a certain base time 
(C)    The ‘six-tenths factor  rule’  is used to  estimate  the cost  of  an  equipment from  the  cost of  a similar equipment with  a different  capacity
 (D)   Payback period is calculated based on the  payback  time for the  sum  of  the fixed and the working capital investment 

Ans:: D)

Q.23  India  has  no  elemental sulphur  deposits  that  can  be  economically  exploited.  In  India, which  one  of the  following  industries produces elemental sulphur as a  by-product? 

(A)  Coal  carbonisation plants 
(C)  Paper  and pulp  industries
 (B)   Petroleum refineries 
(D)  Iron and steel making plants 

Ans:: D)





Q.25


Ans:: A)




Q.31  A jacketed  stirred  tank with a  provision  for  heat removal is  used  to  mix sulphuric  acid and  water in a steady  state  flow  process.  H2SO4  (l)  enters  at a rate  of  4  kg/h at 25oC and H2O (l) enters  at a rate of 6 kg/h at 10oC.  The following data are available: 


Specific  heat  capacity  of  water = 4.2 kJ  kg‒1K‒1. Specific  heat  capacity  of  aqueous solution of  40  mass%  H2SO4  =  2.8 kJ  (kg  solution)‒1  K‒1. 

Assume  the specific  heat  capacities to  be independent  of  temperature.
 Based  on reference states  of H2SO4  (l) and  H2O (l) at  25oC,  the  heat of  mixing for aqueous  solution of 40 mass% H2SO4 = ‒ 650 kJ (kg H2SO4)‒1. 

If  the  mixed  stream  leaves  at  40oC,  what  is the rate  of  heat removal  (in  kJ/h)? 
(A)   1802      (B)   2558.         (C)    5702.   (D)    6458 


Ans:: A)

Q.32  An ideal  gas  is  adiabatically  and  irreversibly  compressed  from 3  bar and  300 K to  6  bar in  a  closed system. The work  required  for the irreversible  compression  is 1.5 times the work that is required for reversible  compression  from  the same  initial temperature  and pressure  to  the  same  final pressure. The  molar  heat  capacity  of  the gas at constant volume is 30  J  mol‒1  K‒1  (assumed  to be  independent of  temperature); universal  gas constant,  R  is  8.314 J  mol‒1  K‒1; ratio of  molar heat capacities  is 1.277.  The temperature (in  K, rounded  off  to the first  decimal  place) of  the gas  at  the final  state in the irreversible compression case is _______ 


Ans::   372.9 K

Q.33  A gas  obeying  the Clausius  equation  of  state is isothermally  compressed from  5  MPa to  15 MPa in a closed system at 400 K.  The Clausius equation of state is  where  P  is the  pressure,  T  is the temperature,   is the  molar volume  and  R  is the  universal gas constant.  The parameter  b  in  the above equation  varies  with temperature  as       with    410 m3mol‒1 and 1.35 10 m3mol‒1K‒1.  The effect of pressure  on  the  molar  enthalpy  (h)  at a constant temperature is given by . Let  hi  and  hf  denote the initial  and  final  molar enthalpies, respectively.  The  change  in the molar enthalpy  first decimal place) for this process is _______ 


Q.35  Water (density=1000 kg  m‒3)  is  pumped  at a  rate  of 36  m3/h,  from a tank 2 m below  the pump, to  an overhead  pressurized  vessel  10  m above  the pump.  The  pressure values at  the point of  suction  from the  bottom  tank and  at the  discharge point to the overhead  vessel  are 120  kPa and 240  kPa, respectively.   All  pipes in  the  system  have the  same diameter.  Take  acceleration due  to  gravity,   g  =  10 m s‒2. Neglecting  frictional losses,  what is  the  power (in kW)  required to  deliver the fluid?


 (A)   1.2.           (B)    2.4         (C)    3.6.     (D)    4.8 







Q.41  In  an experimental setup,  mineral oil is  filled  in between  the  narrow  gap  of two horizontal  smooth plates. The setup  has  arrangements to  maintain  the  plates  at  desired uniform  temperatures.  At these temperatures,  ONLY the  radiative heat flux is negligible.  The  thermal conductivity  of  the oil does not  vary  perceptibly  in this temperature  range.  Consider  four  experiments at steady  state under different  experimental  conditions, as  shown in  the figure  below. The  figure  shows  plate temperatures and the heat fluxes in the vertical direction. 








What is  the  steady  state heat flux (in  W  m‒2)  with the  top  plate at  70oC  and  the bottom  plate at 40oC? 


(A)   26.        (B)    39.          (C)    42            (D)    63 


Ans::  A) 26

Q.42  The  space between  two hollow concentric spheres  of radii  0.1  m  and 0.2 m  is  under vacuum. Exchange  of  radiation (uniform  in  all directions)  occurs only  between  the  outer surface (S1) of  the smaller  sphere  and the  inner surface  (S2)  of the larger sphere.  The  fraction  (rounded  off to  the second decimal place) of the radiation energy leaving S2, which reaches S1 is _______ 

Ans:::    0.25


Q.43  A binary  distillation column  is to  be  designed  using  McCabe  Thiele  method. The distillate contains 90  mol% of  the  more  volatile component. The  point  of intersection of  the  q-line with the equilibrium  curve is  (0.5, 0.7). The  minimum  reflux  ratio  (rounded off  to  the  first decimal  place) for this operation is _______ 



Q.45  At 30℃ amounts of acetone adsorbed at partial pressure 





Q.49  A  porous pellet with  Pt dispersed in  it is  used  to  carry  out a  catalytic reaction. Following  two scenarios are possible.  Scenario  1: Pt  present throughout the  pores of the  pellet is  used for  catalyzing the  reaction.   Scenario  2: Pt  present  only in the immediate vicinity  of  the  external surface of the pellet is used for catalyzing the reaction. 

Scenario  1: Pt  present throughout the  pores of the  pellet is  used for  catalyzing the  reaction.

 Scenario  2: Pt  present  only in the immediate vicinity  of  the  external surface of the pellet is used for catalyzing the reaction. At a  large value  of Thiele  modulus,  which  one of  the  following statements is TRUE?

 (A)   Since the reaction rate  is  much  greater than  the  diffusion  rate,  Scenario  1 occurs
 (B)    Since  the  reaction rate  is  much  greater than the  diffusion rate ,  Scenario  2 occurs
 (C)   Since  the  reaction rate is  much lower than  the diffusion  rate,  Scenario  1 occurs 
(D)   Since the reaction rate is much lower than the diffusion rate, Scenario 2 occurs 




Q.52 A PI controller with integral time constant of 0.1 min is to be designed to control a process with transfer function 








Assume the transfer functions of the measuring element and the final control element are both unity 1,1. The gain (rounded off to the first decimal place) of the controller that will constitute the critical condition for stability of the PI feedback control system is _______ 



Q.53 For a unit step input, the response of a second order system is  

What is the natural period of oscillation (in seconds) of the system?  

(A)   15.9                   (B)   50                    (C)    63.2                    (D)   100

Ans:: D) 100



Q.54 A vertical cylindrical tank with a flat roof and bottom is to be constructed for storing 150 m3 of ethylene glycol. The cost of material and fabrication for the tank wall is Rs 6000 per m2 and the same for the roof and the tank bottom are Rs 2000 and Rs 4000 per m2, respectively. The cost of accessories, piping and instruments can be taken as 10% of the cost of the wall. 10% of the volume of the tank needs to be kept free as vapour space above the liquid storage. What is the optimum diameter (in m) for the tank?

  (A)   3.5.             (B)   3.9.        (C)    7.5.         (D)    7.8 




Q.55  A catalytic  reforming  plant produces  hydrogen and  benzene from  cyclohexane by  de-hydro aromatisation. In  order to  increase the production  of  hydrogen,  the owner  plans  to  change the process to  steam  reforming  of the  same  feedstock  that  produces  hydrogen  and carbon  dioxide. Stoichiometrically,  what  is  the maximum  ratio of  pure  hydrogen produced  in  the proposed process to  that  in the existing process? 

  (A)   1            (B)    2.                 (C)    5              (D)    6 


Ans:: D) 6




                    END OF THE QUESTION PAPER 











Tuesday, March 3, 2015

Thermodynamics

                                                            Thermodynamics

PERSONAL NOTES::

1 st Law Of Thermodynamics

Concepts::

~Energy conservation
~Energy can not be  created nor destroyed but can change its form.
~Heat is a form of energy
~Absolute  values of internal energies cant be calculated
~If heat is added to a system then it has a + sign convection
~If work is done by the system it has a -  sign convection

Gibbs Phase Rule

It determines minimum no of intensive variables that must be arbitarirly fixed to fix all the other properties iof the system.
The phse ruke variables are the Temperature, Pressure and the Composition.

At F=0 system in invarient, Then maximum no of pahses that can exist in equilibrium in given by P= 2+N

At equilibrium driving forces are zero

Chemical potential causes mass to flow across phases rather concentraction difference

                                  PVT BEHAVIOR OF PURE FLUIDS

When  a fuel is burned under adiabatic conditions in the presence of oxygen or air , the maximum temp. attained by the system is called the adiabatic flame temperature.
Max temp. is attainable when the fuel  is burned in the theoretically amount of pore oxygen.
Combustion in the presence of excess air or the oxygen will have adiabatic flame temp less than the maximum attainable theoretical adiabatic flame temp.
Flame temperature calculation are applicable for the exothermic reactions only.


The terms B/V, B/V2 etc of the virial expansion depends upon molecular interaction in ideal gases such interaction do not exist

When Papproches to 0  volume increses and term like B/v approaches to less contribution
Hence as P approaches 0  Z approaches 1

Internal energy is a function of temperature and pressure.
But for an ideal gas it is the function of Temperature only
For an ideal gas cp, cv, Δu, Δ H are all functions of functions of temperature only

                                           2nd Law Of Thermodynamics

Concepts

Heat is a less useful form of energy in contrast to the forms like electrical, mechanical or work
Work can be converted into other forms of energy and neglecting the frictional losses the                    conversion can approach to the efficiency of 100%
It is impossible by a cyclic process to convert heat absorbed by the system to convert completely        into work done
No engine can have efficiency greater than that of Carnot engine operating between same temperature levels.
The thermal efficiency of the Carnot engine depends only on the temperature levels and not  upon the       working substance of the engine.
Coefficient of performance (COP) of heat pumps can never be infinity.

Entropy
The entropy change of a heat reservoir is always given by Q/T
Entropy change is a state function and change is identical whether the change is bought about by a      reversible or irreversible processes


Appliactions of Thermodynamics
Turbines
Turbines uses superheated steam as working fluid exoands to convert internal energy as shaft work of the turbine.
Work of a turbine is
Ws= H2-H1
Isentropic work of a turbine is the maximum work obtainable from expansion process of a aturbine
Efficiency, n= Ws/w(isentropic)=ΔH/ΔH isentropic
Efficiency of an expander is in the range 0.7 to 0.8
Isentropic expansion results in greater change in enthalpy and hence more work
Isentropic expansion is proceede at constant entropy
Calculations are first made for isentropic expansion and then taking into consideration efficiency for actual expansio calculations

Monday, March 2, 2015

Bracket Support Solved Example::

::Problem~01::

Design a bracket support for a vertical cylinder vessel with the help of following data :

  1. Diameter of vessel = 3 m
  2. Height of vessel = 20 m
  3. Clearance from vessel bottom to foundation = 2.0 m
  4. weight of vessel with contents = 5 Tons
  5. Wind pressure = 120-150 kg/m2
  6. No. of brackets = 4 m
  7. Diameter Of anchor bolt circle = 1.65 m
  8. Height of bracket from foundation = 3.0 m
  9. permissible steel structure :
  • Tension = 14.0 kg/cm2
  • Compression = 1240 kg/cm2
  • Bending = 1500 kg/cm2

  1. Permissible bearing pressure
  • From concrete = 38 kg/cm2
View Solution



Saturday, February 14, 2015

Condenser Thermal Design:: Solved Examples

Problem.1

28000 kg/hr of pure ethyl alcohol at 2 psi is to be condensed by water from 85 degree F to 120.
A dirt factor of 0.003 should be provided. A pressure drop at 2 psi is allowable for vapour and 10 psi for the water. Calculate the required size of a 1-2 horizontal condenser using 1 inch OD, 14 BWG, Tubes 16 ft long on 1 1/4 inch triangular pitch.

View solution::

Problem.2

30000 kg/hr of pure ethyl alcohol at 2 psi is to be condensed by water from 85 degree F to 125 Degree F. A dirt factor of 0.004 should be provided. A pressure drop at 2 psi is allowable for the vapour and 10 psi for the water.

Calculate the required size of 1-2 horizontal condenser using 1 inch OD 14 BWG, tubes 16 ft long on 1 1/4 inch triangular pitch.

View solution::

Problem.3

A horizontal 1-2 condenser is required for the condenser of 27200 kg/hr of substantially pure n-propyl alcohol coming from top of distilling column operating at 15 psig at which pressure it boils at 118 Degree C. Water at 29.5 degree C will be used as the cooling medium. A dirt factor of 0.003 is required with allowable pressure drops of 2.0 psi for the vapour pressure and 10 psi for the water.

Assume that 8 ft tubes are used. Tubes are to be 3/4 Inch OD. 16 BWG on 15/16 Inch triangular pitch. Assume fan tube passes and the maximum baffle spacing. Design the condenser.

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Rotary Drier Design Example

Problem.1 

A rotary drier using counter-current flow is to be used to dry 12000 kg/hr of wet salt containing 5% water (wet basis). Heated air at 147 Degree C with 50 Degree C wet bulb temp is available. The specific heat of the salt is 0.21. The outlet temp of air and salt are 72 degree C and 93 degree C respectively. Calculate the length and diameter of the drier required.

DATA::

Humidity of entering air = 0.05 kg water/kg dry air
Mass velocity of air = 5000 kg/hr-m2
Spe. Heat of salt = 0.21 kcal/kg. C

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